4-(Prop-2-yn-1-ylsulfanyl)-1H-pyrazolo[3,4-d]pyrimidine

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4-(Prop-2-yn-1-yl­oxy)benzaldehyde

In the title mol-ecule, C10H8O2, all non-H atoms are essentailly coplanar (r.m.s. deviation = 0.0192 Å), indicating an effective conjugation of the carbonyl group, the benzene ring and the lone pair of the propyn-yloxy O atom. In the crystal, π-π stacking inter-actions [centroid-centroid distance = 3.5585 (15) Å] connect mol-ecules into inversion dimers which are linked by Csp-H⋯O=C hydrogen bo...

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4-Phenyl-1-(prop-2-yn-1-yl)-1H-1,5-benzodiazepin-2(3H)-one

4-Phenyl-1H-1,5-benzodiazepin-2(3H)-one reacts in the pres-ence of a concentrated aqueous solution of sodium hydroxide and a quaternary ammonium salt (as catalyst) in benzene (phase transfer catalysis) with propargyl bromide, affording the title benzodiazepine derivative, C(18)H(14)N(2)O. In the mol-ecule, the mean plane of the propargyl substituent is almost perpendicular with that of the amid...

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Crystal structure of 4-(prop-2-yn-1-yl­oxy)benzo­nitrile

In the title compound, C10H7NO, the dihedral angle between the aromatic ring and the prop-2-yn-1-yl-oxy grouping is 9.47 (10)°. The bond lengths indicate electronic conjugation between the cyano group, the benzene ring and the propyn-yloxy oxygen atom. In the crystal, a hydrogen bond between the acetyl-enic C-H atom and the cyano nitro-gen atom link the mol-ecules into wave-like [30-1] C(11) ch...

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2-Methyl-3-{2-nitro-1-[2-(prop-2-yn-1-yl­oxy)phen­yl]eth­yl}-1H-indole

In the title compound, C(20)H(18)N(2)O(3), the indole unit is essentially planar, with a maximum deviation of 0.0197 (18) Å for the N atom and forms a dihedral angle of 78.09 (9)° with the propyne-subsituted phenyl ring. The propyne group is almost linear, the C-C C angle being 176.5 (2)°, and is also in the flagpole position on the O atom. In the crystal, mol-ecules are linked via N-H⋯O and C-...

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4-(Prop-2-yn-1-yl­oxy)benzene-1,2-dicarbonitrile

In the title compound, C(11)H(6)N(2)O, the complete mol-ecule is generated by the application of crystallographic twofold symmetry (the mol-ecule is disordered about this axis). The prop-2-yn-1-yl residue is slightly twisted out of the plane of the benzene ring [C-O-C-C torsion angle = 173.1 (3)°] and is orientated away from the nitrile substituents. In the crystal, supra-molecular chains along...

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ژورنال

عنوان ژورنال: IUCrData

سال: 2017

ISSN: 2414-3146

DOI: 10.1107/s2414314617015267